Influence of local geological data and geographical parameters to assess regional health impact in LCA. Tomsk oblast', Russian Federation application case.

The research paper is aimed to modify the human health impact assessment of Cr in soils. The current article presents the input of several critical parameters for the human health Impact Score (IShum) assessment in soils. The modification of the IShum is derived using geological data - results of neutron activation analysis of soils are used in the IShum calculation; research area is divided using the watersheds and population size and density. Watersheds reflect the local environmental conditions of the territory unlike the administrative units (geographical areas of the studied region) due to their geological independence. The calculations of the characterization factor value underestimate the influence of the population size and density on the final result. Default characterization factor values cannot be considered during the assessment of the potential human health impact for the big sparsely inhabited areas. In case of very low population density, the result will be overrated and underestimated in the opposite case. The current approach demonstrates that the geographical separation in the USEtox model should be specified. The same approach can be utilized for other geo zones due to the accessibility of this information (area size, population size, and density, geological, and landscape features).

Disruption in Circularity? Impact analysis of COVID-19 on ship recycling using Weibull tonnage estimation and scenario analysis method.

The sustainability of the ship recycling industry strongly linked with the global shipping market and international commodity flows. More than 80% of the End of Life (EoL) ships are dismantled in South Asian countries, namely Bangladesh, India, and Pakistan. Due to measures taken to minimize the propagation of the Coronavirus disease (COVID-19), an international supply chain is broken to a historic low, except for certain medical-related urgencies. Due to the disruption of global supply chains, the industry may submerge into uncertainty due to, perhaps, lack of adequate labor force to dismantle increased EoL ships and due to disturbances of vessel transportation to the recycling nations amid strong precautionary measures. Our estimate suggests that about 300 million Gross Tonnage (GT) available for demolition in the next five years and the inability to get them recycled would cost about 20 billion dollars. More importantly, South Asian recycling nations would suffer from economic losses and employment opportunities. In this study, we also apply a scenario analysis technique to understand the impact range of COVID-19 in the short term and in the long term. The disruption is viewed through a circular economy framework, identifying a critical lack of 'global scale' acknowledgment in the circular economy framework. This article suggests that a formalized global scale, paralleled with favorable policies, may reduce supply chain disruption and improve sustainable development in the receiving nations.

Interaction of Copper-Based Nanoparticles to Soil, Terrestrial, and Aquatic Systems: Critical Review of the State of the Science and Future Perspectives.

In the past two decades, increased production and usage of metallic nanoparticles (NPs) have inevitably increased their discharge into the different compartments of the environment, which ultimately paved the way for their uptake and accumulation in various trophic levels of the food chain. Due to these issues, several questions have been raised on the usage of NPs in everyday life and have become a matter of public health concern. Among the metallic NPs, Cu-based NPs have gained popularity due to their cost-effectiveness and multifarious promising uses. Several studies in the past represented the phytotoxicity of Cu-based NPs on plants. However, comprehensive knowledge is still lacking. Additionally, the impact of Cu-based NPs on soil organisms such as agriculturally important microbes, fungi, mycorrhiza, nematode, and earthworms is poorly studied. This review article critically analyses the literature data to achieve a more comprehensive knowledge on the toxicological profile of Cu-based NPs and increase our understanding of the effects of Cu-based NPs on aquatic and terrestrial plants as well as on soil microbial communities. The underlying mechanism of biotransformation of Cu-based NPs and the process of their penetration into plants have also been discussed herein. Overall, this review could provide valuable information to design rules and regulations for the safe disposal of Cu-based NPs into a sustainable environment.

Towards integrating toxicity characterization into environmental studies: case study of bromine in soils.

AbstractPollution from bromine and some of its related compounds is currently unregulated in soil from Russia and other countries, and tools for sound assessment of environmental impacts of bromine contamination are largely missing. Hence, assessing potential implications for humans and ecosystems of bromine soil contamination is urgently needed, which requires the combination of measured soil concentrations from environmental studies and quantified potential toxicity impacts. To address this need, we used data from an experimental study assessing bromine in soils (384 samples) of Tomsk oblast, Russia, starting from measured concentrations obtained by Instrumental Neutron Activation Analysis in an earlier study. From these data, we calculated the bromine mass in soils and used these as starting point to characterize related cumulative impacts on human health and ecosystems in the Tomsk region, using a global scientific consensus model for screening-level comparative toxicity characterization of chemical emissions. Results show that the combination of sampling methodology with toxicity characterization techniques presents a new approach to be used in environmental studies aimed at environmental assessment and analysis of a territory. Our results indicate that it is important to account for substance-specific chemical reaction pathways and transfer processes, as well as to consider region-specific environmental characteristics. Our approach will help complement environmental assessment results with environmental sustainability elements, to consider potential tradeoffs in impacts, related to soil pollution, in support of improved emission and pollution reduction strategies.

Influence of scope definition in recycling rate calculation for European e-waste extended producer responsibility.

Efficiency indicators have been frequently used to assess end-of-life chain performance, mostly. In terms of the percentage of mass sent to re-use, recycling, and/or energy recovery facilities. While legislation gives a standard definition for recycling and recovery rates, stakeholders sometimes redefine them to better fit their own scopes and objectives. Therefore, to accurately interpret the results of an efficiency indicator, during a decision-making process, it's necessary to fully understand the scope definition used to calculate it. This work discusses the influence of scope definition when establishing performance rates. It does this by introducing further alternative scope definitions and comparing them to those defined by legislation and stakeholders. As a case study, the proposed complementary scopes are applied to the recycling chain of flat panel displays in France.

A regional approach for the calculation of characteristic toxicity factors using the USEtox model.

The lack of the spatial coverage as one of the main limitations of the Life-cycle impact assessment (LCIA) models leads to disagreement between their results. The USEtox model is only model that provides 8 continental and 17 subcontinental zones but does not consider the wind and water transfers affected areas around the source of pollution. Current investigation proposes the way to reduce this limitation by using the results of chemical analysis (instrumental neutron activation analysis "INAA") of pork meat as a regional indicator of anthropogenic influence. The concentration coefficient of Cr by replacing the Bioaccumulation factor (BAF) is extrapolated into the calculation of Exposure factor (XF) to modify Characterization factor (CF). Impacted and clean areas of Tomsk district (Russia) placed around Northern industrial hub (Seversk city) are studied. Neither area is located directly in the industrial hub, but the impacted area is under an anthropogenic influence due to air and water transfer of pollution. Results of our investigation present the difference between results of own investigation and default values of USEtox. Probably the model can minimize the impact because of lack of experiment data in the database. The database can be extended more with other analytical results for wide range of metals and geographical locations.

Fate and Characterization Factors of Nanoparticles in Seventeen Subcontinental Freshwaters: A Case Study on Copper Nanoparticles.

The lack of characterization factors (CFs) for engineered nanoparticles (ENPs) hampers the application of life cycle assessment (LCA) methodology in evaluating the potential environmental impacts of nanomaterials. Here, the framework of the USEtox model has been selected to solve this problem. On the basis of colloid science, a fate model for ENPs has been developed to calculate the freshwater fate factor (FF) of ENPs. We also give the recommendations for using the hydrological data from the USEtox model. The functionality of our fate model is proved by comparing our computed results with the reported scenarios in North America, Switzerland, and Europe. As a case study, a literature survey of the nano-Cu toxicology values has been performed to calculate the effect factor (EF). Seventeen freshwater CFs of nano-Cu are proposed as recommended values for subcontinental regions. Depending on the regions and the properties of the ENPs, the region most likely to be affected by nano-Cu is Africa (CF of 11.11 × 10(3) CTUe, comparative toxic units) and the least likely is north Australia (CF of 3.87 × 10(3) CTUe). Furthermore, from the sensitivity analysis of the fate model, 13 input parameters (such as depth of freshwater, radius of ENPs) show vastly different degrees of influence on the outcomes. The characterization of suspended particles in freshwater and the dissolution rate of ENPs are two significant factors.

E-waste management and resources recovery in France.

There are various issues of concern regarding electronic waste management, such as the toxicity of hazardous materials and the collection, recycling and recovery of useful resources. To understand the fate of electronic waste after collection and recycling, a products and materials flow analysis should be performed. This is a critical need, as material resources are becoming increasingly scarce and recycling may be able to provide secondary sources for new materials in the future. In this study, we investigate electronic waste systems, specifically the resource recovery or recycling aspects, as well as mapping electronic waste flows based on collection data in France. Approximately 1,588,453 t of new electrical and electronic equipment were sold in the French market in 2010. Of this amount, 430,000 t of electronic waste were collected, with the remaining 1,128,444 t remaining in stock. Furthermore, the total recycled amounts were 354,106 t and 11,396 t, respectively. The main electronic waste materials were ferrous metals (37%), plastic (22%), aluminium (12%), copper (11%) and glass (7%). This study will contribute to developing sustainable electronic waste and resource recycling systems in France.

Modeling cumulative effects in life cycle assessment: the case of fertilizer in wheat production contributing to the global warming potential.

This paper aims at presenting a dynamic indicator for life cycle assessment (LCA) measuring cumulative impacts over time of greenhouse gas (GHG) emissions from fertilizers used for wheat cultivation and production. Our approach offers a dynamic indicator of global warming potential (GWP), one of the most used indicator of environmental impacts (e.g. in the Kyoto Protocol). For a case study, the wheat production in France was selected and considered by using data from official sources about fertilizer consumption and production of wheat. We propose to assess GWP environmental impact based on LCA method. The system boundary is limited to the fertilizer production for 1 ton of wheat produced (functional unit) from 1910 to 2010. As applied to wheat production in France, traditional LCA shows a maximum GWP impact of 500 kg CO2-eq for 1 ton of wheat production, whereas the GWP impact of wheat production over time with our approach to dynamic LCA and its cumulative effects increases to 18,000 kg CO2-eq for 1 ton of wheat production. In this paper, only one substance and one impact assessment indicator are presented. However, the methodology can be generalized and improved by using different substances and indicators.